Two-electron three-centered bond in side-on (eta2) uranyl(V) superoxo complexes.
نویسندگان
چکیده
Theoretical calculations suggest a novel two-electron three-atom bonding scheme for complexation of O 2 with U(V) compounds, leading to the stabilization of superoxo complexes in the side-on (eta (2)) configuration. This binding motif is likely to play an important role in the oxidative processes involving trans-uranium compounds having valence 5f phi electrons.
منابع مشابه
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ورودعنوان ژورنال:
- The journal of physical chemistry. A
دوره 112 26 شماره
صفحات -
تاریخ انتشار 2008